Question. Substances P and Q have the same mass and are both solids at temperature T₁. The graph shows how the temperature of each substance varies with the energy transferred to it. Which statement is correct?
- AP has a higher melting point than Q.
- BThe specific latent heat of fusion of P is smaller than that of Q.
- CThe specific heat capacity of solid P is greater than that of solid Q.
- DAt temperature T₂, P is a gas while Q is a solid.
Read the graph in three stages: the slope while the substance is solid, the flat plateau where it melts, and where T₂ sits relative to the two plateaux.
- Let FP and FQ be the melting points (the temperatures of the flat sections). The graph gives FP < FQ.
- While still solid, E = mcΔT, so the slope of the T–E line is 1/(mc). The slope for P is shallower, therefore cP > cQ.
- The length of the plateau is the energy needed to melt the whole sample, E = lΔm. P's plateau is longer, so lP > lQ.
- T₂ lies above FP but below the boiling point of P, and below FQ: at T₂ P is liquid and Q is still solid.
| A | ✗ | The plateau of P is at a lower temperature, so P melts earlier; its melting point is lower, not higher. |
| B | ✗ | A longer plateau means more energy is absorbed at the melting point for the same mass, so lP is larger. |
| C | ✓ | The shallower rise in temperature for the same energy means P stores more energy per kelvin: cP > cQ. |
| D | ✗ | T₂ is above P's melting point but below its boiling point, so P is a liquid there, not a gas. |